Recent experimental discoveries in axis-dependent conduction polarity, or goniopolarity, have observed that the charge carriers can conduct like either electrons or holes depending on the crystallographic direction they travel along in layered compounds such as NaSn₂As₂. The original theoretical proposal is based on the opposite signs of the carrier effective mass, or the curvature of the Fermi surface, without examining the effect of electron lifetimes, thus leaving a crucial question to address. To elucidate this unusual transport behavior, we present an ab initio study of electron scattering in such systems. We study different microscopic scattering mechanisms in NaSn₂As₂, and we present the electron-phonon scattering time distribution on its Fermi surface in momentum space, the open concave shape of which is proposed to be the origin of the axis-dependent conduction polarity. Further, we obtain the overall anisotropic lifetime tensors in real space at different electron chemical potentials and temperatures, and we discuss how they contribute to the macroscopic thermopower. While we find that the contribution of the in-plane and cross-plane lifetimes exhibits a similar trend, the concave portion of the Fermi surface alters the electron motion significantly in the presence of a magnetic field, thus flipping the conduction polarity as measured via the Hall effect. Our calculations and analysis of NaSn₂As₂, in comparison with similar systems, also suggest the strong possibility of hydrodynamic electron flow in the system. Finally, our work has implications for anisotropic electron lifetimes in a broad class of goniopolar materials and provides key, general insights into electron scattering on open Fermi surfaces.